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guideword
stringclasses
7 values
meaning
stringlengths
37
81
parameter
stringlengths
4
18
example_deviation
stringlengths
21
81
example_cause
stringlengths
73
112
example_consequence
stringlengths
86
150
example_safeguard
stringlengths
104
194
NO/NOT
Complete negation of the design intent (the intended event does not occur at all)
Flow
No flow in process pipe to reactor
Control valve CV-101 fails closed; pump P-201 fails to start; blocked line upstream
No feed to reactor — potential runaway if exothermic reaction already in progress; catalyst damage
Low-flow alarm FAL-101; reactor temperature high alarm TAH-201; interlock on reactor feed shutdown; pump duty-standby auto-changeover
NO/NOT
Complete negation of the design intent
Reaction
No reaction in batch vessel
Catalyst not loaded; incorrect raw material; temperature too low to initiate
Off-spec batch; undetected unreacted hazardous material in product stream; downstream explosion risk on concentration
Batch recipe interlocks; temperature confirmation before heat release; in-process quality sample; production hold and test procedure
NO/NOT
Complete negation of the design intent
Level
No level in separator
Bypass valve left open draining vessel; upstream failure; drain left open
Loss of liquid seal in separator — gas breakthrough to liquid outlet; overpressure in downstream liquid line; downstream fire
Low-level alarm LAL-201; low-low level shutdown LSL-201LL; operator checklist for drain valve position before startup
MORE
Quantitative increase above the design intent
Flow
More flow through heat exchanger shell side
Upstream control valve CV-202 fails open; increased upstream pressure; pressure regulator failure
Tube overloading; elevated pressure on tube-side — tube failure; flammable or toxic material release to cooling water or atmosphere
High-flow alarm FAH-202; pressure relief valve PRV-HX101 on shell; shell inspection programme for tube integrity
MORE
Quantitative increase above the design intent
Temperature
High temperature in reactor
Excessive steam supply; blocked cooling water; runaway exothermic reaction; loss of agitation
Decomposition; runaway reaction; vessel overpressure; BLEVE potential for flammable material; toxic gas release
High temperature alarm TAH-301; high-high temperature shutdown TSH-301HH (trips steam supply + activates quench); relief valve RV-R01; agitator low-speed trip
MORE
Quantitative increase above the design intent
Pressure
High pressure in gas storage vessel
Thermal expansion (solar radiation); upstream compressor runaway; blocked outlet; external fire (BLEVE scenario)
Vessel failure; BLEVE; fragment projection; vapour cloud explosion; multiple casualties
Pressure relief valve PSVX-01; rupture disk upstream of PSV; high-pressure alarm PAH-401; fire-fighting water system; vessel support design for fire case
MORE
Quantitative increase above the design intent
Level
High level in atmospheric tank
Inlet control valve fails open; level transmitter failure; operator inattention during filling
Overflow of flammable / toxic material; tank berm exceedance; environmental spill; fire risk
High-level alarm LAH-501; high-high level shutdown LSH-501HH (closes inlet valve); independent level gauge (sight glass); overfill protection device per API 2350
MORE
Quantitative increase above the design intent
Concentration
Higher concentration of hazardous component in reactor feed
Sampling error; supplier batch variation; metering error; wrong raw material loaded
Runaway reaction; product out of spec; potential detonation for peroxide-forming substances
Inlet analyser AIC-601; feed ratio control; batch record verification; raw material QC certificate check
LESS
Quantitative decrease below the design intent
Flow
Less flow in cooling water to reactor jacket
Cooling water pump degradation; partial valve closure; fouling in cooling water circuit
Inadequate heat removal; reactor temperature rise; runaway risk; potential decomposition of thermally sensitive material
Low cooling water flow alarm FAL-701; temperature rise alarm TAH-301; interlock on reactor agitator speed and steam supply
LESS
Quantitative decrease below the design intent
Temperature
Low temperature in cryogenic storage vessel
Refrigeration system failure; excessive heat ingress; warm product fill; vacuum jacket failure
Vapour generation; pressure build-up; relief valve lifting; potential vessel embrittlement if temperature falls below design minimum metal temperature
Low temperature alarm TAL-801; high pressure alarm PAH-401; refrigeration duty-standby; boil-off gas management system; vessel material specification for cryogenic service
LESS
Quantitative decrease below the design intent
Level
Low level in suction vessel
Outlet valve opens unexpectedly; downstream demand increase; metering error
Pump cavitation; loss of flow downstream; potential air ingestion; product quality impact; pump seal failure
Low-level alarm LAL-201; pump auto-stop on low-low level LSLL; inlet control valve override to maintain minimum level
LESS
Quantitative decrease below the design intent
Pressure
Low pressure in reactor (vacuum scenario)
Condenser flooding; outlet valve opens; steam condensation with no vent; cold snap with no nitrogen padding
Vessel designed for pressure operation only — implosion; ingress of air into flammable atmosphere; oxygen contamination of product
Vacuum relief valve VRV-R01; nitrogen padding system with N2 supply alarm; pressure monitoring with low-pressure alarm PAL
AS WELL AS
Qualitative modification — something in addition to what was intended
Composition / Flow
Contaminant in process stream — water in anhydrous reactor feed
Condensation in delivery hose; improper purging after hydrotest; water hold-up in dead leg
Decomposition of water-sensitive catalyst; violent reaction with moisture-reactive material; steam generation causing overpressure
Moisture analyser on feed; purge and dry-out procedure after maintenance; line draining checklist; dead-leg elimination programme
AS WELL AS
Qualitative modification — additional hazardous material present
Two-phase flow
Gas and liquid carried together in normally liquid line
Vaporisation due to pressure drop; gas ingestion at pump suction; dissolved gas release
Surge and slug flow causing pipe vibration; fatigue failure; flow measurement error; pump damage; high vibration and noise
Separator upstream of pump; vortex breaker; flow pulsation dampener; vibration monitoring on pump and critical pipework
PART OF
Qualitative modification — only part of the intended event occurs
Composition
Partially complete chemical reaction — low conversion
Catalyst poisoning; insufficient residence time; low temperature; reactant ratio imbalance
Unreacted hazardous material in product stream; downstream processing of out-of-spec stream; potential for secondary undesired reaction
In-line analyser on reactor outlet; batch sample testing with hold procedure; residence time interlock on continuous reactor
PART OF
Only part of intended transfer completes
Flow (partial)
Partial transfer of batch to next vessel — incomplete drain
Pipe partially blocked; valve does not fully open; pump operates below design duty
Wrong batch composition in receiving vessel; heel material causes contamination in next batch
Level confirmation in source and destination vessels before process step sign-off; batch management system check
REVERSE
Logical opposite of the design intent
Flow
Reverse flow in single-direction line
Downstream pressure higher than upstream; pump fails while line is pressurised; siphon effect on drain line
Back-flow of product (possibly hazardous) into wrong vessel or to atmosphere; contamination; overfill
Non-return valve (check valve) NRV-101; backflow prevention device; interlock preventing simultaneous opening of inlet and outlet valves; reverse flow alarm in DCS
REVERSE
Logical opposite — reversed rotation or direction
Rotation
Pump / compressor reverse rotation
Single phasing of motor; incorrect phase connection after maintenance; loss of supply phase
No flow or reduced flow; potential seal failure; motor overheating; damage to impeller
Anti-rotation device on pump; phase rotation indicator on motor starter; electrical protection relay; pre-start check procedure
OTHER THAN
Complete substitution — something completely different from design intent
Material / Service
Wrong material charged to reactor
Label mix-up; look-alike containers; wrong tank connection; material substitution without MOC
Uncontrolled reaction; toxic gas release; equipment damage; potential fatality; fire/explosion
Material labelling and colour-coding; two-person verification on material loading; unique connection fittings (key locks); MOC procedure; pre-charge verification checklist
OTHER THAN
Deviation in utility service — wrong service applied
Utility
Wrong utility connected — instrument air connected to nitrogen line or vice versa
Physical connection error during maintenance; connector not uniquely designed; labelling failure
Instrument air in purge system — oxygen ingress into inerted system; fire/explosion; or nitrogen in breathing air line — asphyxiation
Unique connection fittings for different services; colour-coding of pipe and hose connections; cross-connection prevention programme; pressure and composition check after reconnection
OTHER THAN
Operating mode deviates from intended
Operating mode
Maintenance mode operated instead of production mode (or vice versa)
Logic controller fault; software update error; HMI display error; operator selection error
Safety instrumented system bypassed; safety interlocks defeated without authorisation; process run outside safe operating limits
Access control on operating mode selection; mode change requires authorised sign-off; SIS bypass log and management procedure (IEC 61511 management of functional safety); proof testing programme

HAZOP Guidewords Reference 2026 — IEC 61882 with Node Examples

HAZOP guidewords reference following IEC 61882:2016 and CCPS guidance. 7 standard guidewords (NO/NOT, MORE, LESS, AS WELL AS, PART OF, REVERSE, OTHER THAN) applied to key process parameters (flow, pressure, temperature, level, composition, reaction, rotation, operating mode) with ~20 worked examples each providing: deviation, cause, consequence, and safeguard.

Dataset details

Suggested citation

SmartQHSE Ltd (2026). HAZOP Guidewords Reference 2026 — IEC 61882 with Node Examples [dataset]. Zenodo. https://doi.org/10.5281/zenodo.20171699

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Disclaimer

This dataset is published for reference, training, and research. Regulatory text and action levels are summarised; consult the authoritative source listed before basing operational or compliance decisions on this dataset. SmartQHSE Ltd accepts no liability for errors or omissions.

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